coloring 2001D
Paste 2001D
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Manufactured By: Shanghai DAOKOW PU Material CO. ,LTD.
No.1,Lane 628,Zhudai Road,Zhu Bridge Industrial Park,Shanghai
Preparer: PRODUCT STEWARDSHIP COMPLIANCE AND STANDARDS
Contact numbers: Emergency Response (24 hours): (86)-21-59963900 (Chinese)
Fax:(86)-21-59963955
Chemical Family/Use: Used in the manufacturing of polyurethane foam.
HMIS
Flammability: 1 Reactivity: 0 Health: 1
NFPA
Flammability: 1 Reactivity: 0 Health: 1
2. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
WARNING! Causes eye irritation.
Form: paste Color: red Odor: No
POTENTIAL HEALTH EFFECTS
INGESTION
slightly toxic May cause the following effects: – abdominal discomfort nausea Vomiting
SKIN
No evidence of harmful effects from available information.
INHALATION
Short-term harmful health effects are not expected from vapor generated at ambient temperature.
EYES
Causes irritation. Causes the following effects: – stinging Discomfort Pain May cause the
following effects: – excess redness of the conjunctivae – swelling of the conjunctivae
MEDICAL CONDITIONS AGGRAVATED
A knowledge of the available toxicology information and of the physical and chemical properties
of the material suggests that overexposure is unlikely to aggravate existing medical conditions.
SUBCHRONIC (TARGET ORGAN )
None known.
CHRONIC EFFECTS / CARCINOGENICITY
This product or one of its ingredients present at 0.1% or more is NOT listed as a carcinogen or
ROUTES OF EXPOSURE
3. COMPOSITION/INFORMATION ON INGREDIENTS
PRODUCT COMPOSITION CAS REG NO. WGT. %
A. HAZARDOUS
NOT contained
B. NON-HAZARDOUS
Sun-resistant 27580-14-9 25%
Polyether 9003-11-6 75%
4. FIRST AID MEASURES
INGESTION
If conscious, drink plenty of water. Induce vomiting, but only if victim is fully conscious. Obtain
medical attention.
SKIN
Immediately remove contaminated clothing and shoes. Wash skin thoroughly with soap and water
for at least 15 minutes. Obtain medical attention.
INHALATION
Remove to fresh air. Obtain medical attention.
EYES
Immediately flush eyes with water and continue washing for at least 15 minutes. Obtain medical
attention if symptoms persist.
NOTE TO PHYSICIAN
There is no specific antidote. Treatment is symptomatic and supportive.
5. FIRE-FIGHTING MEASURES
FLASH POINT: 104 °C; 219 °F
METHOD: ASTM D 93
IGNITION TEMPERATURE: No data available
FLAMMABLE LIMITS IN AIR – LOWER (%): No data available
FLAMMABLE LIMITS IN AIR – UPPER (%): No data available
EXTINGUISHING MEDIA
All standard extinguishing agents are suitable.
SPECIAL FIRE FIGHTING PROCEDURES
Firefighters must wear NIOSH/MSHA approved positive pressure self-contained breathing
apparatus with full face mask and full protective clothing.
6. ACCIDENTAL RELEASE MEASURES
ACTION TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED
Wipe, scrape or soak up in an inert material and put in a container for disposal. Wash walking surfaces
with detergent and water to reduce slipping hazard. Wear proper protective equipment as specified in
the protective equipment section.
ENVIRONMENTAL PRECAUTIONS
Do not flush into surface water or sanitary sewer system.
7. HANDLING AND STORAGE
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE
Avoid contact with skin and eyes. Keep away from children. Attention: Not for injection into humans.
May generate formaldehyde at temperatures greater than 150 C (300 F). See Section 10 of MSDS for
details.
STORAGE
Keep container closed. Store in original container.
FURTHER INFORMATION ON STORAGE CONDITIONS
No data available
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
ENGINEERING CONTROLS
Use only in an area equipped with a safety shower.; Eye wash bottle with pure water; General
(mechanical) room ventilation is expected to be satisfactory if handled at low temperatures or in covered
equipment.; Special, local ventilation is needed at points where vapors can be expected to escape to the
workplace air.
RESPIRATORY PROTECTION
If exposure limits are exceeded or respiratory irritation is experienced, NIOSH/MSHA approved
respiratory protection should be worn. Supplied air respirators may be required for non-routine or
emergency situations. Respiratory protection must be provided in accordance with OSHA regulations
(see 29CFR 1910.134).
PROTECTIVE GLOVES
Impermeable or chemical resistant gloves.
EYE AND FACE PROTECTION
Safety glasses with side-shields
OTHER PROTECTIVE EQUIPMENT
Wear suitable protective clothing and eye/face protection.
Exposure Guidelines
Component CAS RN Source Value
Absence of values indicates none found
PEL – OSHA Permissible Exposure Limit; TLV – ACGIH Threshold Limit Value; TWA – Time Weighted Average; INTL REL – Internal
Recommended Exposure Limit
OSHA revoked the Final Rule Limits of January 19, 1989 in response to the 11th Circuit Court of Appeals decision (AFL-CIO v. OSHA)
effective June 30, 1993. See 29 CFR 1910.1000 (58 FR 35338).
9. PHYSICAL AND CHEMICAL PROPERTIES
BOILING POINT – C & F: > 150 °C; > 302 °F; Copolymer
VAPOR PRESSURE (20℃) (MM HG): <1
VAPOR DENSITY (AIR=1): >1
FREEZING POINT: < 0 °C; < 32 °F
PHYSICAL STATE: slurry
ODOR: mild
COLOR: red
EVAPORATION RATE (BUTYL ACETATE=1): <1
DENSITY(20℃): 1.5g/cm3
ACID / ALKALINITY (MEQ/G): No data available
pH: No data available
VOLATILE ORGANIC CONTENT (VOL): No data available
SOLUBILITY IN WATER (20℃): soluble
VOC EXCL. H2O & EXEMPTS (G/L): 521
10. STABILITY AND REACTIVITY
STABILITY
Stable
HAZARDOUS POLYMERIZATION
Will not occur.
HAZARDOUS THERMAL DECOMPOSITION / COMBUSTION PRODUCTS
Burning can produce the following combustion products:; Carbon oxides; Oxides of silicon.;
formaldehyde; Carbon monoxide is highly toxic if inhaled; carbon dioxide in sufficient concentrations can
act as an asphyxiant.; Acute overexposure to the products of combustion may result in irritation of the
respiratory tract.; This product contains methylpolysiloxanes which can generate formaldehyde at
approximately 300 degrees Fahrenheit (150’C) and above, in atmospheres which contain oxygen.
Formaldehyde is a skin and respiratory sensitizer, eye and throat irritant, acute toxicant, and potential
cancer hazard. A MSDS for formaldehyde is available from Momentive.
INCOMPATIBILITY (MATERIALS TO AVOID)
None known.
CONDITIONS TO AVOID
None known.
11. TOXICOLOGICAL INFORMATION
ACUTE ORAL
Remarks: Unknown
ACUTE DERMAL
Remarks: Unknown
ACUTE INHALATION
Remarks: Unknown
OTHER
No data available
SENSITIZATION
No data available
SKIN IRRITATION
No data available
EYE IRRITATION
No data available
MUTAGENICITY
Unknown
OTHER EFFECTS OF OVEREXPOSURE
No adverse effects anticipated from available information.
12. ECOLOGICAL INFORMATION
ECOTOXICOLOGY
All available ecological data have been taken into account for the development of the hazard and
precautionary information contained in this Safety Data Sheet.
13. DISPOSAL CONSIDERATIONS
DISPOSAL METHOD
Disposal should be made in accordance with federal, state and local regulations.
14. TRANSPORT INFORMATION
Further Information: This product is not regarded as dangerous goods according to the national
and international regulations on the transport of dangerous goods.
15. REGULATORY INFORMATION
Inventories
Korea Existing Chemicals
Inventory (KECI)
Japan Inventory of Existing & New
Chemical Substances (ENCS)
EU list of existing chemical
substances
Australia Inventory of Chemical
Substances (AICS)
Philippines Inventory of Chemicals
y (positive listing)
y (positive listing)
y (positive listing)
y (positive listing)
y (positive listing)
and Chemical Substances
(PICCS)
TSCA list y (positive listing)
China Inventory of Existing
y (positive listing)
Chemical Substances
Canada DSL Inventory y (positive listing)
For inventories that are marked as quantity restricted or special cases, please contact Momentive.
US Regulatory Information
SARA (311,312) HAZARD CLASS
Acute Health Hazard
SARA (313) CHEMICALS
CALIFORNIA PROPOSITION 65
This product does not contain any chemicals known to State of California to cause cancer, birth, or any
other reproductive defects.
Canadian Regulatory Information
WHMIS HAZARD CLASS
D2A – Very Toxic Material Causing Other Toxic Effects
D2B – Toxic Material Causing Other Toxic Effects
HMIRC Information
Registry number: 6,987
16. OTHER INFORMATION
OTHER
These data are offered in good faith as typical values and not as product specifications. No warranty,
either expressed or implied, is made. The recommended industrial hygiene and safe handling
procedures are believed to be generally applicable. However, each user should review these
recommendations in the specific context of the intended use and determine whether they are
appropriate., C = ceiling limit NEGL = negligible EST = estimated NF = none found NA
= not applicable UNKN = unknown NE = none established REC = recommended ND = none
determined V = recommended by vendor SKN = skin TS = trade secret R =
recommended MST = mist NT = not tested STEL = short term exposure limit ppm = parts
per million ppb = parts per billion By-product= reaction by-product, TSCA inventory status not
required under 40 CFR part 720.30(h-2).
